wiz-icon
MyQuestionIcon
MyQuestionIcon
1
You visited us 1 times! Enjoying our articles? Unlock Full Access!
Question

Between cuprous and cupric which is more stable and why

Open in App
Solution

Cupric which is copper(II) is more stable than Cuprous, copper(I).
The standard reduction potentials of copper at 25C:

Cu2+ + 2e- -> Cu, E = +0.34V
Cu+ + e- -> Cu, E = +0.15V

This means that, subtracting one equation from the other,

Cu2 + e- -> Cu+, E = +0.19V.

It takes only 0.19V of energy to oxidize Cu+ to Cu2+, so in the earth's atmosphere that is 1/5 oxygen, there is plenty of oxidizing power around to scavenge Cu+ ions. Compare this to the theoretical minimum potential difference needed to split water to make oxygen and hydrogen, ~1.2V

On the other hand, you can't oxidize copper any further than Cu2+ (Cupric). You can't strip any more electrons away, so it is stable in the earth's atmosphere.

flag
Suggest Corrections
thumbs-up
1
Join BYJU'S Learning Program
similar_icon
Related Videos
thumbnail
lock
Dihydrogen - Preparation Methods; Physical and Chemical Properties; Uses
CHEMISTRY
Watch in App
Join BYJU'S Learning Program
CrossIcon