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Elimination Reactions of Alkyl Halides

Bicyclohexane...

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Bicyclohexane was found to undergo parallel first order reactions at 730K to form cyclohexane and methyl cyclopentene. Rate constant for the formation of cyclohexane was 1.26×10^-4 /s andfor the formation of methyl cyclopentene was 3.8×10^-5/sec . Fraction of cyclohexane in the product is ?

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Q. Bi-cyclohexane was found to undergo two parallel first order rearrangements. At

730 K

, the first order rate constant for the formation of cyclohexane was measured as

1.26 \times 10^{- 4} s^{- 1}

and for the formation of methyl cyclopentene the rate constant was

3.8 \times 10^{- 5} s^{- 1}

%

distribution of the rearrangement products.

Q. A substance '

A

' was found to undergo two parallel first order reactions, i.e.,

A \to B

A \to C

, with rate constants

1.26 \times 10^{- 4} s^{- 1}

3.8 \times 10^{- 5} s^{- 1}

respectively. What were the percentage distribution of

B

C

?

Q. What is the total number of products formed on monochlorination of 1 methyl cyclohexane?

Q. Compare the stabilities of the following two compounds (A) and (B):
A:

c i s - 1 - e t h y l - 3 - m e t h y l

c y c l o h e x a n e

t r a n s - 1 - e t h y l - 3 - m e t h y l

c y c l o h e x a n e

Q. cis-1-chloro-2 methyl cyclohexane is subjected to dehydrohalogenation by E2 mechanism. The product is

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Elimination Reactions of Alkyl Halides

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