Boiling point of alkyl iodide, bromide, chloride and methane are in which of the following order?

I o d i d e > B r o m i d e > C h l o r i d e > C H_{4}

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C H_{4} > C h l o r i d e > B r o m i d e > I o d i d e

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C H_{4} > I o d i d e > B r o m i d e > C h l o r i d e

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C h l o r i d e > B r o m i d e > I o d i d e > C H_{4}

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Solution

The correct option is A $I o d i d e > B r o m i d e > C h l o r i d e > C H_{4}$
Boiling point order
$I o d i d e > B r o m i d e > C h l o r i d e > C H_{4}$
As the size and mass of halogen atom increases, van der Waal's forces increases, hence boiling point increases.

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