CameraIcon
CameraIcon
SearchIcon
MyQuestionIcon
MyQuestionIcon
1
You visited us 1 times! Enjoying our articles? Unlock Full Access!
Question

Boiling point of chloroform is 61C. After addition of 5.0 g of a non-volatile solute to 20 g chloroform boils at 64.63C. If Kb=3.63 K kg mol1, what is the molecular weight of the solute?

A
320 g/mol
No worries! We‘ve got your back. Try BYJU‘S free classes today!
B
100 g/mol
No worries! We‘ve got your back. Try BYJU‘S free classes today!
C
400m g/mol
No worries! We‘ve got your back. Try BYJU‘S free classes today!
D
250 g/mol
Right on! Give the BNAT exam to get a 100% scholarship for BYJUS courses
Open in App
Solution

The correct option is D 250 g/mol
Given,
b.p. of chloroform = 61C
New b.p. after addition = 64.63C
Mass of solute, w2=5.0g
Mass of solvent, w1=20g
Kb=3.63Kkgmol1
From these, ΔTb=64.6361=3.63C
Using ΔTb=(Kb×1000×w2)(M2×w1)
M2=(Kb×1000×w2)(ΔTb×w1)
M2=(3.63×1000×5)(3.63×20)=250 g/mol.

flag
Suggest Corrections
thumbs-up
4
Join BYJU'S Learning Program
similar_icon
Related Videos
thumbnail
lock
Elevation in Boiling Point
CHEMISTRY
Watch in App
Join BYJU'S Learning Program
CrossIcon