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Question

Boron can be obtained by various methods but not by ;

A
pyrolysis of Bl3 (Van Arkel).
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B
reducing BCl3 with H2.
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C
electrolysis of fused BCl3.
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D
thermal decomposition of B2H6.
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Solution

The correct option is C electrolysis of fused BCl3.
Electrometallurgy is used for the extraction of highly electropositive metals such as sodium, potassium, magnesium, calcium and aluminum. Boron is not a highly electropositive metal. Hence, boron cannot be obtained by the electrolysis of fused BCl3

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