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Question

Both lithium and magnesium display several similar properties due to the diagonal relationship. However, the one which is incorrect is:

A
Both form soluble bicarbonates
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B
Both from nitrides
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C
Nitrates of both Li and Mg yield NO2 and O2 on heating
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D
Both form basic carbonates
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Solution

The correct option is D Both form basic carbonates
Common properties of lithium and magnesium are:
  • Similar size
  • Atomic radii
  • Harder and lighter than other elements
  • Oxides and hydroxides are insoluble in water and soluble in ethanol
  • They form nitrides,
  • They do not combine with excess oxygen to form superoxides
  • Nitrates of both yield NO2 and O2 on heating
  • Their carbonates decompose easily
  • They are deliquescent
  • They form soluble bicarbonates
  • Both can form carbonates but lithium carbonate is not basic in nature.

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