Both Mg and Fe metal can reduce copper from a solution having Cu2+ ion, according to equilibria. Mg(s)+Cu2+⇋Mg2++Cu(s);K1=6×1090 Fe(s)+Cu2+⇋Fe2++Cu(s);K2=3×1026
Choose the correct option regarding above equilibrium.
A
Mg removes more Cu2+ from solution
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B
Fe removes more Cu2+ from solution
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C
Both will equally remove Cu2+ from solution
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D
Both metals cannot remove Cu2+ from solution
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Solution
The correct option is AMg removes more Cu2+ from solution Since, K1>K2, the product in the first reaction is much more favoured than in the second one. Mg thus removes more Cu2+ from solution than Fe does.