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Question

Br2 reacts with O2 in either of the following ways depending upon supply of O2.
Br2+12O2Br2O ;

Br2+32O2Br2O3
In the first list reactants are present and in second list the products are given. Match the list.

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Solution

In limited supply of oxygen, Br2O is obtained.
In excess supply of oxygen, Br2O3 is obtained.
(A) When 320 g of Br2 is mixed with 64 g of O2, 1 mole (Br2O) and 1 mole of (Br2O3) are obtained.
(B) When 160 g of Br2 is mixed with 8 g ofO2, 12 mole of (Br2O) and 12 mole of (Br2) are obtained.
(C) When 80 g of Br2 is mixed with 32 g of O2, 12 mole of (Br2O3) and 14 mole of O2 are obtained.
(D) When 160 g of Br2 is mixed with 48 g of O2, 1 mole Br2O3 is obtained.

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