The correct option is D Carbonic acid
Buffer system of body consists of three individual buffers- carbonate or carbonic acid, phosphate buffer and the buffering of plasma proteins.
Blood neutralizes the metabolic acids produced by its high base concentration.
Sodium carbonate by itself is not a buffer, its just alkaline solution. A mixture of sodium carbonate and sodium bicarbonate is a buffer.
So, the correct answer is -carbonic acid.