By the reaction of carbon and oxygen, a mixture of CO and CO2 is obtained. The mass ratio of the mixture obtained when 20 g of O2 reacts completely with 12 g of carbon is:
A
mCO:mCO2=21:11
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B
mCO:mCO2=11:21
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C
mCO:mCO2=22:14
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D
mCO:mCO2=14:22
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Solution
The correct option is DmCO:mCO2=21:11 Given: Moles of C=1212=1
Moles of O2=2032=0.625 Reaction:
Let the moles of oxygen which react with C to form CO2 be x 2C+O2→2CO 1−x(1−x)/21−x C+O2→CO2 xxx We have, (1−x)/2+x=0.625
Hence, x=0.25
So, moles of carbon dioxide is equal to 0.25 and moles of carbon monoxide is equal to 0.75 .
So, mass of CO produced is 21 g and mass of CO2 produced is 11 g.