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Byju's Answer
Standard XII
Chemistry
Nomenclature of Carboxylic Acid Derivatives
C13H10O A B +...
Question
C
13
H
10
O
C
F
3
C
O
3
H
−
−−−−−
→
(
A
)
H
3
O
+
−
−−
→
B
+
C
With neutral
F
e
C
l
3
,
C
gives violet colour. B on decarboxylation and C on reduction with zinc dust, gives same compound. The correct statement is:
A
C gives dye test positive in weakly alkaline medium
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B
C gives dye test positive in weakly acidic medium
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C
C gives dye test positive in strongly alkaline medium
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D
B can be formed by oxidation of toluene with chromyl chloride
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Solution
The correct option is
A
C gives dye test positive in weakly alkaline medium
Starting compound is benzophenone.
B is benzoic acid and C is phenol.
Phenol gives azo dye test at a pH around 9-10.
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Similar questions
Q.
C
13
H
10
O
C
F
3
C
O
3
H
−
−−−−−
→
(
A
)
H
3
O
+
−
−−
→
B
+
C
With neutral
F
e
C
l
3
,
C
gives violet colour. B on decarboxylation and C on reduction with zinc dust, gives same compound. The correct statement is:
Q.
C
13
H
10
O
C
F
3
C
O
3
H
−
−−−−−
→
(
A
)
H
3
O
+
−
−−
→
B
+
C
With neutral
F
e
C
l
3
,
C
gives violet colour. B on decarboxylation and C on reduction with zinc dust, gives same compound. The correct statement is:
Q.
An organic compound (A) of molecular formula
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6
H
6
O
gives violet colour with neutral ferric chloride. Compound (A) when heated with zinc dust gives a hydrocarbon (B). Also compound (A) reacts with phthalic anhydride and conc.
H
2
S
O
4
to give compound (C) of molecular formula
C
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14
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4
. Identify (A), (B) and (C). Explain the reactions.
Q.
Chloroform on reduction with zinc dust and water gives
Q.
A ketone A
(
C
4
H
8
O
)
, which undergoes haloform reaction gives compound B on reduction. B on heating with sulphuric acid gives a compound C which forms mono-ozonide D. D on hydrolysis in presence of zinc dust gives only acetaldehyde E. Identify A, B, C, D and E. Write the reactions involved.
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