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Question

C2H5ClMoist−−−→Ag2O(A)360oC−−−→Al2O3(B)S2Cl2−−−→(C)
In the above sequence of reaction, identify (C)

A
Chloretone
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B
Chloropicrin
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C
Mustard gas
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D
Lewisite gas
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Solution

The correct option is B Mustard gas
concept:
  • Ethyl chloride on treatment with moist silver oxide forms ethanol.
  • Ethanol on heating with alumina to a temperature of 350oC forms ethene.
  • Ethene reacts with S2Cl2​ to form mustard gas (compound C).

C2H5Clmoist Ag2O−−−−−−C2H5OHAl2O3,350oC−−−−−−−CH2=CH2S2Cl2−−ClCH2CH2SCH2CH2Cl
mustard gas

The compound C is mustard gas. and Option C is correct answer.

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