2.58⋅1024 carbon atoms.
The molecular formula of propanol is C3H8O.
First, we should calculate its molecular mass. I prefer to work with rounded numbers because that's how I was taught and frankly it makes life much easier. You should have memorized that the molar masses of carbon, hydrogen, and oxygen are, respectively, 12gmol, 1gmol and 16gmol
So let's add all that up:
M=(3⋅12)+(8⋅1)+(1⋅16)
M=60gmol
Okay, but that doesn't tell us much by itself. Elements make up substances in different proportions, because they have different masses, so how much of propanol is actually carbon, in terms of percentage? Remember, 36 g of that is carbon:
60g→100%36g→x%}⇒x=60%
So now we know that any given sample of propanol is sixty percent carbon. Now we can use the information that we were given: 85.9g. If that's the total mass of propanol, sixty percent of that must be carbon:
85.9g→100%yxg→60%}⇒y=51.54g
Now, let us return to the concept of a mole. A mole is a quantity of 6⋅1023 of something. You might be used to using a more accurate value, but for now let us use that simplified number. Molar mass is the mass of a mole of something; so 6⋅1023 atoms of carbon have a total mass of 12g. With that in mind, we can now work out how many atoms of carbon have a total mass of 51.54g:
6⋅1023atoms→12gzxatoms→51.54g}⇒z=2.58⋅1024atoms