$C_{6} H_{5} N O_{2} C l_{2} / F e - --- \to$

m-chloronitrobenzene

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m-dichloronitrobenzene

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1,3,5 tri-chlorobenzene

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chlorobenzene

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Solution

The correct option is A m-chloronitrobenzene
Nitro group on benzene ring is a meta directing group. So, when the nitrobenzene is treated with chlorine in presence of iron, metachloro nitrobenzene is formed.

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C_{6} H_{6} +^{'} X^{'} . . . . \to C_{6} H_{5} N O_{2}

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C_{6} H_{6} +^{'} X^{'} \to C_{6} H_{5} N O_{2}

^{'} X^{'}

C_{6} H_{5} N O_{2} \to C_{6} H_{5} N H_{2}

C_{6} H_{5} N O_{2} + K O H (s) H e a t - -- \to o - n i t r o p h e n o l + p - n i t r o p h e n o l

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