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Question

C−Cl bond of chlorobenzene in comparison to C−Cl bond of methyl chloride is:

A
longer and weaker
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B
shorter and weaker
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C
shorter and stronger
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D
longer and stronger
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Solution

The correct option is C shorter and stronger
The CCl bond in C6H5Cl is shorter than in CH3Cl and therefore, stronger.

The lone pair on chlorine are dispersed throughout the benzene ring by resonance. This gives the CCl bond a double bond character.

Option C is correct.

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