C(s)+O2(g)−→CO2(g)ΔH∘=−393.5 kJ mol−1 C(s)+12O2(g)−→CO(g)ΔH∘=−110.5 kJ mol−1 H2(g)+12O2(g)−→H2O(g)ΔH∘=−241.8 kJ mol−1
The standard enthalpy change ( in kJ mol−1) for the reaction. CO2(g)+H2(g)⟶CO(g)+H2O(g) is
A
−262.2
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B
+41.2
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C
−41.2
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D
+262.2
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Solution
The correct option is B+41.2 Answer (2) CO2(g)→C(s)+O2(g)+393.5kJ mol−1 C(s)+12O2(g)→CO(g)−110.5kJ mol−1 H2(g)+12O2(g)→H2O(g)−241.8 kJ mol−1
Adding: CO2(g)+H2(g)→CO(g)+H2O(g) ΔH∘rnx=(+393.5−110.5−241.8)kJmol−1 =41.2 kJmol−1