Copper sulphate generally exists as copper sulphate pentahydrate form (CuSO4.5H2O) which is in blue colour. When it comes in contact with sulphuric acid which is a hygroscopic substance, it absorbs water molecules from copper sulphate pentahydrate.
As all the water molecules get absorbed by sulphuric acid, the white crystals of anhydrous copper sulphate are produced.