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Byju's Answer
Standard XII
Chemistry
Relation between Cp and Cv
CP -CV for an...
Question
C
P
−
C
V
for an ideal gas is
R
.
State whether the statement is True or False
Open in App
Solution
According to the first law of thermodynamics:
Δ
Q
=
Δ
U
+
Δ
W
⇒
Δ
W
=
P
Δ
V
Δ
Q
P
=
Δ
U
+
P
Δ
V
Since
Δ
Q
p
=
n
C
p
Δ
T
and
Δ
U
=
n
C
v
Δ
T
, therefore,
n
C
p
Δ
T
=
n
C
v
Δ
T
+
P
Δ
V
(
1
)
We know that
P
V
=
n
R
T
At
T
1
K
e
l
v
i
n
:
P
V
1
=
n
R
T
1
.....(a)
At
T
2
K
e
l
v
i
n
:
P
V
2
=
n
R
T
2
.....(b)
Subtracting (a) from (b)
P
V
2
−
P
V
1
=
n
R
T
2
−
n
R
T
1
P
(
V
2
−
V
1
)
=
n
R
(
T
2
−
T
1
)
P
Δ
V
=
n
R
Δ
T
Putting the value of
P
Δ
V
in equation (1)
n
C
p
Δ
T
=
n
C
v
Δ
T
+
n
R
Δ
T
n
C
p
Δ
T
=
n
Δ
T
(
C
v
+
R
)
C
p
=
(
C
v
+
R
)
C
p
−
C
v
=
R
Hence the statement is
True
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P
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V
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P
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V
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P
−
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V
=
R
for an ideal gas. Reason:
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∂
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]
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=
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for an ideal gas
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p
−
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v
for an ideal gas is xR.
So, the value of x is ______.
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