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Question

CPCV for an ideal gas is R.
State whether the statement is True or False

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Solution

According to the first law of thermodynamics:
ΔQ=ΔU+ΔWΔW=PΔV
ΔQP=ΔU+PΔV

Since ΔQp=nCpΔT
and ΔU=nCvΔT , therefore,
nCpΔT=nCvΔT+PΔV (1)

We know that PV=nRT
At T1Kelvin:PV1=nRT1.....(a)
At T2Kelvin:PV2=nRT2.....(b)

Subtracting (a) from (b)
PV2PV1=nRT2nRT1
P(V2V1)=nR(T2T1)
PΔV=nRΔT

Putting the value of PΔV in equation (1)
nCpΔT=nCvΔT+nRΔT
nCpΔT=nΔT(Cv+R)
Cp=(Cv+R)
CpCv=R
Hence the statement is True

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