The correct option is
D 145To get C(s)→C(g)
C(s)+O2(g)→CO2(g)→CO2(g);ΔH=−94−3...(1)
CO(g)+12O2(g)→CO2(g);ΔH=−67−4...(2)
C2(g)→2O(g);ΔH=117.4...(3)
CO(g)→C(g)+O(g);ΔH=230.6...(4)
Eqn.(1)−(2)−(3)×12+(4)
C(s)+O2(g)→CO2ΔH=−94.3...(1)
−CO(g)+12O2→CO2ΔH=−67.4...(2)
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C(s)+12O2(g)→COΔH=−26.9
−12O2(g)→O(g)ΔH=117.42...(3)
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C(s)→CO(g)−O(g);ΔH=−85.6
+CO(g)→C(g)+O(g);ΔH=230.6...(4)
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C(s)→C(g);ΔH=145kcal