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Question

C(s)+O2(g)CO2,(g); ΔH=94.3 kcal/mol
CO(g)+12O2(g)CO2(g); ΔH=67.4 kcal/mol
O2(g)2O(g); ΔH=117.4 kcal/mol
CO(g)C(g)+O(g); ΔH=230.6 kcal/mol.
Calculate ΔH for C(s)C(g) in kcal/mol.

A
17.1
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B
154
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C
117
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D
145
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Solution

The correct option is D 145
To get C(s)C(g)
C(s)+O2(g)CO2(g)CO2(g);ΔH=943...(1)
CO(g)+12O2(g)CO2(g);ΔH=674...(2)
C2(g)2O(g);ΔH=117.4...(3)
CO(g)C(g)+O(g);ΔH=230.6...(4)
Eqn.(1)(2)(3)×12+(4)
C(s)+O2(g)CO2ΔH=94.3...(1)
CO(g)+12O2CO2ΔH=67.4...(2)
____________________________________
C(s)+12O2(g)COΔH=26.9
12O2(g)O(g)ΔH=117.42...(3)
____________________________________
C(s)CO(g)O(g);ΔH=85.6
+CO(g)C(g)+O(g);ΔH=230.6...(4)
_____________________________________
C(s)C(g);ΔH=145kcal

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