Ca2+ can be determined by precipitating it as CaC2O4 gravimetrically. The percentage of Ca2+ in a sample, if 0.5 g of Ca2+ salt gave 1.28g of CaC2O4 is Given (Ca=40,Ca=12,O=16)
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Solution
The molar mass of CaC2O4 is 40+2(12)+4(16)=128g/mol
Thus, 128 g CaC2O4 corresponds to 40 g Ca2+.
Hence, 1.28 g CaC2O4 will correspond to 0.4 g Ca2+.
Hence, the percentage of Ca2+ in the sample =0.4g0.5g×100=80%.