Calcium carbonate decomposes on heating according to the equation
CaCO3(s)→CaO(s)+CO2(g)
The volume of CO2 obtained by thermal decomposition of 50 g of CaCO3 at STP will be:
No.of moles of CaCO3 = 50100 =0.5
According to reaction, 1 mole of CaCO3 gives 1 mole of CO2.
So 0.5 moles of CaCO3 will give 0.5 moles of CO2
Now at STP 1 mole of any gas = 22.4 L
So 0.5 moles of CO2 gas = 22.4×0.5 = 11.2 L