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Question 26
Calcium chloride when dissolved in water dissociates into its ions according to the following equation.

CaCl2(aq)Ca2+(aq)+2Cl(aq)

Calculate the number of ions obtained from CaCl2 when 222 g of it is dissolved in water.

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Solution

1 mole of calcium chloride = 40+(35.5 X 2)= 40+71 =111g
222g of CaCl2 is equivalent to 2 moles of CaCl2.

Calcium chloride when dissolved in water dissociates into its ions as given below,
CaCl2(aq)Ca2+(aq)+2Cl(aq)

Here, number of moles of ions in 1 mole of CaCl2 = 3

No. of ions = No. of moles of ions × Avogadro number
Number of ions produced by 111g of CaCl2 =3×6.022×1023
Therefore, number of ions produced by 222g of CaCl2 =3×6.022×1023×222111
=36.132×1023
=3.6132×1024 ions




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