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Question

Calculate CFSE values for the following system.

d5 - high spin octahedral

A
0.0Δ0
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B
2.0Δ0
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C
2.4Δ0
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D
2.0Δ0
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Solution

The correct option is A 0.0Δ0
Option (A) is correct.
In d5- high spin octahedral, 3 electron is their in t2g and 2 electrons in eg.
By applying formula,

Δ for octahedral complex = no. of electrons in eg·(0.6)+ no. of electrons in t2g(-0.4)
=2(0.6)+3(0.4)
=0.0 Δo

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