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Byju's Answer
Standard XII
Chemistry
Hess' Law
Calculate ent...
Question
Calculate enthalpy for formation of ethylene from the following data:
(I)
C
(
g
r
a
p
h
i
t
e
)
+
O
2
(
g
)
→
C
O
2
(
g
)
;
Δ
H
=
−
393.5
k
J
(II)
H
2
(
g
)
+
1
2
O
2
(
g
)
→
H
2
O
(
l
)
;
Δ
H
=
−
286.2
k
J
(III)
C
2
H
4
(
g
)
+
3
O
2
(
g
)
→
2
C
O
2
(
g
)
+
2
H
2
O
(
l
)
;
Δ
H
=
−
1410.8
k
J
A
54.1 kJ
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B
44.8 kJ
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C
51.4 kJ
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D
48.4 kJ
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Solution
The correct option is
C
51.4 kJ
(I)
C
(
g
r
a
p
h
i
t
e
)
+
O
2
(
g
)
→
C
O
2
(
g
)
---- 1
(II)
H
2
(
g
)
+
1
2
O
2
(
g
)
→
H
2
O
(
l
)
----- 2
(III)
C
2
H
4
(
g
)
+
3
O
2
(
g
)
→
2
C
O
2
(
g
)
+
2
H
2
O
(
l
)
---- 3
Desired reaction:
2
C
(
g
r
a
p
i
t
e
)
+
2
H
2
(
g
)
→
C
2
H
4
(
g
)
The desired above reaction can be obtained by multiplying eqn. 1 and 2 by 2 and adding them followed by subtracting eqn. 3 from the sum.
Enthalpy of formation can be calculated as:
Δ
H
f
=
(
2
×
R
e
a
c
t
i
o
n
I
+
2
×
R
e
a
c
t
i
o
n
I
I
−
R
e
a
c
t
i
o
n
I
I
I
)
Δ
H
f
=
(
−
2
×
393.5
−
2
×
286.2
+
1410.8
)
=
51.4
k
J
Suggest Corrections
0
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Q.
Calculate the heat of formation of acetic acid from the following data:
a.
C
(
s
)
+
O
2
(
g
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⟶
C
O
2
(
g
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,
Δ
H
=
−
393.7
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J
b.
H
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c.
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⟶
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+
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H
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k
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Q.
The enthalpy of combustion of benzene from the following data will be:
(i)
6
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(
s
)
+
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H
2
(
g
)
→
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H
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(
l
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;
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H
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k
J
(ii)
H
2
(
g
)
+
1
2
O
2
(
g
)
→
H
2
O
(
l
)
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Δ
H
=
−
285.9
k
J
(iii)
C
(
s
)
+
O
2
(
g
)
→
C
O
2
(
g
)
;
Δ
H
=
−
393.5
k
J
Q.
Find the heat of formation of ethyl alcohol from following data
C
(
s
)
+
O
2
(
g
)
⟶
C
O
2
(
g
)
......
Δ
H
=
−
94
K
c
a
l
H
2
(
g
)
+
I
/
2
O
2
(
g
)
⟶
H
2
O
(
l
)
;....
Δ
H
=
−
68
K
c
a
l
C
2
H
5
O
H
(
l
)
+
3
O
2
(
g
)
⟶
2
C
O
2
(
g
)
+
3
H
2
O
(
l
)
.....
Δ
H
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−
327
K
c
a
l
Q.
Using the following thermochemical data
C
(
S
)
+
O
2
(
g
)
→
C
O
2
(
g
)
,
Δ
H
=
−
94.0
K
c
a
l
H
2
(
g
)
+
1
2
O
2
(
g
)
→
H
2
O
(
l
)
,
Δ
H
=
−
68.0
K
c
a
l
C
H
3
C
O
O
H
(
l
)
+
2
O
2
(
g
)
→
2
C
O
2
(
g
)
+
2
H
2
O
(
l
)
,
Δ
H
=
−
210.0
K
c
a
l
The heat of formation of acetic acid is
Q.
From the following data of heats of combustion, find the heat of formation of
C
H
3
O
H
(
l
)
:
C
H
3
O
H
(
l
)
+
3
2
O
2
(
g
)
⟶
C
O
2
(
g
)
+
2
H
2
O
(
l
)
;
Δ
H
=
−
726
k
J
C
(
s
)
+
O
2
(
g
)
⟶
C
O
2
(
g
)
;
Δ
H
=
−
394
k
J
H
2
(
g
)
+
1
2
O
2
(
g
)
⟶
H
2
O
(
l
)
;
Δ
H
=
−
286
k
J
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