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Question

Calculate moles of KMnO4 required for complete oxidation of 2 moles of KHC2O4.2H2C2O4 under acidic condition.

A
105
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B
65
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C
125
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D
85
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Solution

The correct option is C 125
KHC2O4.2H2C2O4
Each oxalate will lose 2 electrons. it has three oxalate in the formula
Hence, the total n-factor =6
n-factor for KMnO4=5
For a redox reaction,
number of equivalents of the oxidant = number of equivalents of the reductant

number of equivalents of the reductant =moles×n-factor =2×6=12
number of equivalents of KMnO4=12
Hence moles of KMnO4=equivalentsn-factor=125

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