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Question

Calculate osmotic pressure of 3.42% w/V solution of cane sugar (sucrose) at 27C.
Given:
Molecular formula of sucrose is C12H22O11

A
2.46 atm
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B
0.16 atm
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C
4.96 atm
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D
0.08 atm
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Solution

The correct option is A 2.46 atm
Molecular mass of sucrose =(12×12)+(22×1)+(11×16)=342 g mol1
3.42 g of sucrose is present in 100 mL of solution.

Osmotic pressure :
π=nV×RT
Here,
n=3.42342=0.01V=100 mL=0.1 LR=0.0821 L atm mol1 K1T=27C=300 K

π=0.010.1×0.0821×300π=2.46 atm

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