Calculate q.w.ΔU and ΔH for the reversible isothermal expansion of one mole of an ideal gas at 127oC from a volume of 10dm3 to 20dm3.
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Solution
Since, the process is isothermal, ΔU=ΔH=0 From the first law of thermodynamics ΔU=q+w=0 q=−w w=−2.303nRTlogV2V1=−2.303×1×8.314×400log2010 =−2.303×1×8.314×0.3010=−2305.3J (Work done by system) q=−w=2305.3J (Heat absorbed by the system)