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Question

Calculate q.w.ΔU and ΔH for the reversible isothermal expansion of one mole of an ideal gas at 127oC from a volume of 10 dm3 to 20 dm3.

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Solution

Since, the process is isothermal,
ΔU=ΔH=0
From the first law of thermodynamics
ΔU=q+w=0
q=w
w=2.303nRTlogV2V1=2.303×1×8.314×400log2010
=2.303×1×8.314×0.3010=2305.3J (Work done by system)
q=w=2305.3J (Heat absorbed by the system)

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