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Question

Calculate standard entropy change in the reaction
Fe2O3(s)+3H2(g)2Fe(s)+3H2O(l)
Given : S0m(Fe2O3,S)=87.4,S0m(Fe,S)=27.3,S0m(H2,g)=130.7,S0m(H2O,l)=69.9JK1mol1

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Solution

Fe2O3(s)+3H22Fe(s)+3H2O(l)
ΔSoreaction=ΣΔSo(products)ΣΔSo(reactants)
=2Som(Fe,S)+3Som(H2O,l)[Som(Fe2O3,S)+3Som(H2,g)]
=(2×27.3)+(3×69.9)87.4(3×130.7)
ΔSoreaction=-215.2Jk1

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