Let the two vectors be A and B, and their resultant be R.
Let the angle between A and B be θ
A=2N
B=3N
R=4N
Now R2=A2+B2+2ABcosθ
So,42=22+32+2×3×4cosθ
So, 16=4+9+24cosθ
So, 16=13+24cosθ
So, 3=24cosθ
So, 324=cosθ
So, cosθ=1/8
So, θ=cos−1(1/8)