The correct option is C 30.6 eV
Energy required to move an electron from any state to n=∞ is called the binding energy of that state.
So, binding energy = 13.6Z2n2.
For, Li2+, Z=3, n=2 (i.e 1st excited state)
Therefore, binding energy = 13.63222 eV
binding energy = 13.694 eV
Hence binding energy = 30.6 eV