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Question

Calculate the binding energy of an electron in the first excited state of Li2+ ion.

A
35 eV
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B
29.6 eV
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C
30.6 eV
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D
28.9 eV
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Solution

The correct option is C 30.6 eV
Energy required to move an electron from any state to n= is called the binding energy of that state.

So, binding energy = 13.6Z2n2.

For, Li2+, Z=3, n=2 (i.e 1st excited state)
Therefore, binding energy = 13.63222 eV
binding energy = 13.694 eV
Hence binding energy = 30.6 eV

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