Given BEC−H=413 kJ; BEH−Cl=413 kJ
△Hr=∑Hproduct−∑△Hreactant
△Hr=3(C−H)+(C−Cl)+(H−Cl)−4(C−H)−(Cl−Cl)
Putting values of given bond enthalpies
△Hr=326+431−413−(Cl−Cl)
−100.3=326+431−413−(Cl−Cl)
(Cl−Cl)=444.3 kJ