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Question

Calculate the bond energy of ClCl bond from the following data:
CH4(g)+Cl(g)CH3Cl(g)+HCl(g);ΔH=100.3 kJ. Also the bond enthalpies of CH,CCl,HCl bonds are 413,326 and 431 kJmol1 respectively.

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Solution

Given BECH=413 kJ; BEHCl=413 kJ

Hr=HproductHreactant

Hr=3(CH)+(CCl)+(HCl)4(CH)(ClCl)

Putting values of given bond enthalpies

Hr=326+431413(ClCl)

100.3=326+431413(ClCl)

(ClCl)=444.3 kJ

Bond enthalpy of ClCl bond
is 444.3 kJ

971396_786245_ans_18a0f72f76b246e1832963d01e77bee1.PNG

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