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Question

Calculate the composition of the resulting mixture when 450mL of carbon monoxide is mixed with 200mL of oxygen.


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Solution

Step1. Given information

450mL of carbon monoxideCO , 200mL of oxygenO2.

Step2. Application of Gay-Lussac's Law of combining volumes

  • According to this law, when gases react, the ratio of the volume of gaseous reactant to the gaseous product is expressed as a simple whole-number ratio. The conditions required are constant pressure and temperature.
  • This law is only applicable to gases. As a result, the volumes of solids and liquids are assumed to be zero.
  • For the given information, it is applied as follows:

2CO+O22CO22vols1vols2vols

Step3. Calculation of composition of the resulting mixture

1vol of oxygen react with 2vol of carbon monoxide

200mL of oxygen will react with 200mL×2=400mL of carbon monoxide.

Remaining carbon monoxide

=450mL-400mL=50mL

1vol of oxygen produces 2vol of carbon dioxide

200mL of oxygen produces 200mL×2=400mL of carbon dioxide.

Hence, the composition of the resulting mixture is 400mL of carbon dioxide, and 50mL of carbon monoxide.


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