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Question

Calculate the critical temperature of a Van der Waals gas for which Pc=100 atm and b is 0.050 dm3/mol.
Take R=112 l atm/mol K

A
300 K
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B
480 K
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C
420 K
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D
400 K
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Solution

The correct option is B 480 K
Pc=100 atmb=0.050 dm3/molTc=8a27Rba=3PcV2cb=Vc3Vc=3ba=27Pcb2Tc=8×27Pcb227RbTc=8PcbRTc=8×100×1×0.051/12=480 K

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