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Question

Calculate the de-Broglie wavelength associated with the electron in the 2nd excited state of the hydrogen atom. The ground state energy of the hydrogen atom is 13.6 eV.

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Solution

Energy of electron in ground state = 13.6 eV

For the second excited state n=3

The kinetic energy of an electron in a second excited state

E=13.6(3)2=1.51 eV

the the the the the the the the de-Broglie wavelength of an electron in a second excited state

λ=h2 km

λ=6.63×10342×1.51×1.6×1019×9.1×1031 m

λ=6.63×10346.63×1025 m

λ=1×109 m

λ=10×1010 m

λ=10.0 A

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