Calculate the ΔG value from the following data and state whether the process will be spontaneous or non spontaneous at 298K. The heat of reaction is - 85.0 kJ and the entropy change for the reaction is +9.50 J/K.
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Solution
As we know that,
ΔG=ΔH−TΔS
Given:-
ΔH=−85.0kJ
ΔS=+9.50J/K=9.5×10−3kJ/K
T=298K
∴ΔG=−85−(298×9.5×10−3)
⇒ΔG=−85−2.8=−87.8kJ
As the value of ΔG is −ve, therefore the reaction is spontaneous.