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Question

Calculate the electron gain enthalpy of fluorine atom using the following data.
All the values are in kJ mol1 at 25oC. ΔHdiss(F2)=160,ΔfH(NaF(s))=571, I.E. [Na(g)]=494,ΔHvap[Na(s)]=101. Lattice enthalpy of NaF(s)=894.
Also, make Born - Haber's cycle.

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Solution

Lattice energy =ΔHf+ΔHvap(Na)
12ΔHdiss
IEEA
EA=571+10112(160)494894
47080494894
EA=1938 KJmol1.

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