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Question

Calculate the electronegativity of fluorine from the following data:
Bond energy of H-H bond EHH=104.2 kcal mol1
Bond energy of F-F bondEFF=36.6 kcal mol1
Bond energy of H-F bond EHF=134.6 kcal moll
Electronegativity of Hydrogen XH=2.1.

A
3.87
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B
2.76
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C
-3.87
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D
-2.76
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Solution

The correct option is A 3.87
Let the electronegativity of fluorine be XF. Applying Pauling equation,
XFXH=0.208[EHF (EFF ×EHH)0.5]0.5
In this equation, dissociation energies are taken in kcal mol1
XF2.1=0.208[134.6 (104.2 ×36.6)0.5]0.5
XF = 3.87

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