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Byju's Answer
Standard XII
Chemistry
EMF
Calculate the...
Question
Calculate the emf and
Δ
G
o
for the cell reaction at
25
o
C:
Z
n
(
s
)
|
Z
n
2
+
a
q
(
0.1
M
)
|
C
d
2
+
a
q
(
0.01
M
)
|
C
d
(
s
)
Given
E
o
Z
n
2
+
/
Z
n
=
−
0.763
and
E
o
C
d
2
+
/
C
d
=
−
0.403
V
.
Open in App
Solution
Z
n
2
+
+
2
e
−
→
Z
n
;
E
0
Z
n
2
+
/
Z
n
=
−
0.763
V
C
d
2
+
+
2
e
−
→
C
d
;
E
0
C
d
2
+
/
C
d
=
−
0.403
V
Cell reaction:
C
d
2
+
+
Z
n
→
C
d
+
Z
n
2
+
emf of the cell is,
E
0
c
e
l
l
=
0.763
−
0.403
=
0.360
V
Δ
G
0
=
−
n
F
E
0
c
e
l
l
where, n=2 and F=faraday constant = 96485 C/mol
Δ
G
0
=
−
2
×
96485
×
0.36
∴
Δ
G
0
=
69.5
k
J
Suggest Corrections
2
Similar questions
Q.
Write cell representation for following cells :
C
d
2
+
(
a
q
)
+
Z
n
(
s
)
→
Z
n
2
+
(
a
q
)
+
C
d
(
s
)
Q.
Δ
r
G
o
for the cell with the cell reaction:
Z
n
(
s
)
+
A
g
2
O
(
s
)
+
H
2
O
(
l
)
→
Z
n
2
+
(
a
q
)
+
2
A
g
(
s
)
+
2
O
H
−
(
a
q
)
[
E
o
A
g
2
O
/
A
g
=
0.344
V
,
E
o
Z
n
2
+
/
Z
n
=
−
0.76
V
]
Q.
C
u
I
(
s
)
+
e
−
→
C
u
(
s
)
+
I
−
;
E
o
C
u
+
/
C
u
=
−
0.16
V
Z
n
2
+
(
a
q
)
+
2
e
−
→
Z
n
(
s
)
;
E
o
Z
n
2
+
/
Z
n
=
−
0.76
V
Calculate the EMF.
Q.
The emf of a cell corresponding to the reaction
Z
n
(s)
+
2
H
+
(aq)
→
Z
n
2
+
(
0.1
M
)
+
H
2
(
g
,
1
bar
)
is
0.28
V
at
25
∘
C
. Calculate the pH of the solution at the hydrogen electrode. Given
E
∘
Z
n
2
+
|
Z
n
=
−
0.763
V
Q.
The equilibrium constant for the reaction given below at 298 K is if
E
c
e
l
l
=
0.2905
V
at 298 K is:
Z
n
(
s
)
+
F
e
2
+
(
a
q
)
0.01
M
→
Z
n
2
+
0.1
M
(
a
q
)
+
F
e
(
s
)
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