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Question

Calculate the emf of the following concentration cell at 25C;
Ag(s)|AgNO3(0.01 M)AgNO3(0.05 M)|Ag(s).

A
0.414 V
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B
0.828 V
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C
0.414 V
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D
0.0414 V
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Solution

The correct option is D 0.0414 V
E=E0.0591nlog10Q
(E=0 for all concentration cells)
=00.05911log10(0.010.05)
=0.0414 V.

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