Calculate the energy emitted when electrons of 1.0 gram atom of hydrogen undergo transition giving the spectral line of lowest wave energy in the visible region of its atomic spectrum.
A
n2=3 to n1=2;E=182.8KJ
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B
n2=2 to n1=1;E=155.8KJ
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C
n2=3 to n1=1;E=180.8KJ
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D
n2=4 to n1=2;E=182.5KJ
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Solution
The correct option is An2=3 to n1=2;E=182.8KJ For transition of lowest wave energy of Balmer series (visible), the transition is n=3→m=1. Therefore, ΔE=13.6eV×(1/m2−1/n2)=1.89eV=182kJmol−1.