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Question

Calculate the energy in kilocalorie per mol of the photons of an electromagnetic radiation of wavelength 7600˚A.

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Solution

λ=7600˚A=7600×108cm
c=3×1010cms1
Frequency, v=cλ=3×10107600×108=3.947×1014s1
Energy of one photon =hv=6.62×1027×3.947×1014
=2.61×1012erg
Energy of one mole of photons =2.61×1012×6.02×1023
=15.71×1011erg
Energy of one mole of photons in kilocalorie =15.71×10114.185×1010 [1kcal=4.185×1010erg]
=37.538 kcal per mol.

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