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Question

Calculate the entropy change in surroundings when 1.00 mol of H2O(l) is formed under standard conditions. ΔfHθ=286 kJ mol1.

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Solution

It is given that 286 kJ mol1 of heat is evolved on the formation of 1 mol of H2O(l). Thus, an equal amount of heat will be absorbed by the surroundings. q surr=+286kJ mol1
Entropy change (Δ S surr) for the surroundings =q surrT
=286 kJ mol1298 k
Δ S surr=959.73Jmol1K1


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