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Question

Calculate the final volume (in L) of one mole of an ideal gas initially at 0oC and 1 atm pressure, if it absorbs 2000 cal of heat during a reversible isothermal expansion.

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Solution

Let us consider the problem:
AT stp; the gas is the pressure and standard temperature condition
v1=22.4dm3(given)
v2=?(findout)
Let we know that
ΔU=q+w
ΔU=0 (isotherm and resistible for given expression)
q=w=2000cal
=2000×4.184=8368
woek done w=nRT/n(v2v1)
Therefore
w=8368J=Nrt/n(v2v1)
(im01)×(8.314Jk1m011)(273k)/n(v202.5dm)
hence,
v2=242.50dm3

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