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B
-117.86 K cal
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C
116.86 K cal
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D
-116.86 K cal
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Solution
The correct option is B
-117.86 K cal
The required equation is 2C(s)+2H2(g)+O2(g)→CH3COOH(l)△H=? CH3COOH(l)+2O2(g)→2CO2(g)+2H2O(l)△H=−207.9Kcal−−−−−−(i) C(s)+O2(g)→CO2(g)△H=−94.48Kcal−−−−−−(ii) (g)H2+12O2(g)→H2O(l)△H=−68.4Kcal−−−−−−(iii)
Multiply equation (ii) by 2 and also equation (iii) by 2, add both of subtracting equation (i) we get 2C+2O2+2H2+O2−CH3COOH−2O2→2CO2+2H2O−2CO2−2H2O △HCH3COOH=2(−94.48)+2(−68.4)−(−207.9) △HCH3COOH=−117.86Kcal