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Question

Calculate the heat of formation of acetic acid from the following data.

CH3COOH(l) + 2O2(g) 2CO2(g) + 2H2O(l), H= 207.9 K cal
C(s) + O2(g)CO2(g) H = 94.48 K cal
H2(g) + 12O2(g)H2O(l) H = 68.4 K cal

A

117.86 K cal

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B

-117.86 K cal

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C

116.86 K cal

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D

-116.86 K cal

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Solution

The correct option is B

-117.86 K cal


The required equation is 2C(s) + 2H2(g) + O2(g)CH3COOH(l) H = ?
CH3COOH(l) + 2O2(g)2CO2(g) + 2H2O(l) H = 207.9 K cal (i)
C(s) + O2(g)CO2(g) H = 94.48 K cal (ii)
(g)H2 + 12 O2(g)H2O(l) H = 68.4 K cal (iii)
Multiply equation (ii) by 2 and also equation (iii) by 2, add both of subtracting equation (i) we get
2C + 2O2 + 2H2 + O2CH3COOH2O22CO2 + 2H2O2CO22H2O
HCH3COOH = 2(94.48) + 2(68.4)(207.9)
HCH3COOH = 117.86 K cal

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