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Question

Calculate the heat of formation of anhydrous Al2Cl2 from
2Al(s)+6HCl(aq)Al2Cl6(aq)+3H2(g),H=239.76 kcal
H2(g)+Cl2(g)2HCl(g),H=44.0 kcal
HCl(g)+AqHCl(aq),H=17.32 kcal
Al2Cl6(s)+AqAl2Cl6(aq),H=153.69 kcal.

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Solution

2Al(s)+3Cl2(s)Al2Cl6(s)ΔH=?
(i) 2Al(s)+6HCl(aq)Al2Cl6(aq)+3H2(or),ΔH1=239.76kCal
(ii) H2(g)+Cl2(g)2HCl(g),ΔH2=44.0kCal
(iii) HCl(g)+AvHCl(aq),ΔH3=17.32kCal
(iv) Al2Cl6(s)+AqAl2Cl6(aq),ΔH4=153.6kCal
Al2Cl6 formation can be given by :
(i)+3×(ii)6×(iii)(iv)
ΔHAl2Cl6=ΔH1+3×ΔH26×ΔH3ΔH4
={239.76+3×(44.0)6×(17.32)(153.6)}kCal
=114.24kCal

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