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Question

Calculate the heat of hydrogenation of C2H2 to C2H4.
H2(g)+12O2(g)H2O(l);ΔH=68.32kcal
C2H2(g)+12O2(g)2CO2(g)+H2O(l);ΔH=310.61kcal
C2H4(g)+3O2(g)2CO2(g)+H2O(l);ΔH=337.32kcal

A
141.61 kcal
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B
41.61 kcal
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C
41.61 kcal
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D
None of these
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Solution

The correct option is B 41.61 kcal
Heat of hydrogenation = heat of formation of water + heat of combustion of C2H2 - heat of combustion of C2H4
heat of hydrogenation =68.32+(310.61)(337.32) = 41.61kcal

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