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Question

Calculate the mass of ascorbic acid (Vitamin C,C6H8O6 to be dissolved in 75 g of acetic acid to lower its melting point by 11.5C.Kf=3.9K Kg mol1


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Solution

Given:
ΔTf=1.5C or K,Kf=3.9 K kg mol1
Mass of acetic acid (wA)=75 g
Molar mass of ascorbic acid (MB)=176 g mol1
Mass of ascorbic acid

We know that, ΔTf=Kf×molality(m)
We also know, molality(m)=mass of solute(B)molar mass of solute(B)×mass of solvent(A)(in kg)

So, ΔTf=Kf×wBMB×wA

1.5K=3.9KKgmol1×WB176gmol1×75×103kg

WB=1.5×75×176×1033.9=5.077g

Hence, required mass of ascorbic acid is 5.077 g.


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