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Question

Calculate the mass of ice needed to cool 150g of water contained in a calorimeter of mass 50g at 32oC such that the final temperature is 5oC.
Specific heat capacity of calorimeter 0.4Jg-1C-1o
Specific heat capacity of water 4.2Jg-1C-1o
Latent heat capacity of ice 330Jg-1


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Solution

Step 1: Given Data

Mass of water m1=150g
Initial temperature of water T1=32oC
Specific heat capacity of water s1=4.2Jg-1C-1o
Mass of calorimeter m2=50g
The initial temperature of the calorimeter T1=32oC

Specific heat capacity of water s2=0.4Jg-1C-1o

The final equilibrium temperature given as T=5oC

Step 2:Calculate the heat lost

  1. We want to add ice in the water so that ice immediately melts and the temperature should become T=5oC. For this, we will calculate the heat energy required to be released in order to make its temperature fromT1=32oC toT=5oC .
  2. heat lost=heat lost by water+heat lost by calorimeter

Or, heat lost=m1s1T1-T+m2s2T1-T=150×4.232-5+50×0.4×(32-5)

Or,heat lost=m1s1T1-T+m2s2T1-T=150×4.232-5+50×0.4×(32-5)

Or, heat lost=17550J

Step 3: Calculate the mass of ice

Now this heat lost will be gained by ice. Upon gaining this much heat, ice will immediately melt into water.

Therefore, mass of requiredm=QL, where L is the Latent heat capacity of ice 330Jg-1. And we obtained heatQ=17550J.

So, the Amount of heat gain for melting is

Q1=mLQ1=m×330Q1=330m

The amount of heat gain for changing the temperature of ice is,

Q2=ms1T-0∘Q2=m×4.2×5∘-0∘Q2=21m

As the amount of heat gained is equal to the amount of heat lost thus,

Q1+Q2=heatlost330m+21m=17550351m=17550m=50kg

Thus, the mass of ice needed to cool the calorimeter in the given situation will be 50g.


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