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Question

Calculate the mass percent of different elements present in sodium sulphate (Na2SO4).

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Solution

Step 1: Definition and formula of mass percent:

Mass percent is a way of expressing a concentration or describing the component in a particular mixture. The solution composition can be described in mass percentage which shows the mass of solute present in a given mass of solution

Formula of mass percent –

𝑀𝑎𝑠𝑠 𝑝𝑒𝑟𝑐𝑒𝑛𝑡 𝑜𝑓 𝑎𝑛 𝑒𝑙𝑒𝑚𝑒𝑛𝑡=mass of that element in the compoundmolar mass of the compound×100

Step 2: Molar mass of an element.

Description:

According to the given question

The molecular formula of sodium sulphate is (Na2SO4)

Therefore, Molar mass = gram atomic mass of sodium + gram atomic mass of Sulphur + gram atomic mass of Oxygen

Or, we can write

𝑀𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠

=𝑔𝑟𝑎𝑚 𝑎𝑡𝑜𝑚𝑖𝑐 𝑚𝑎𝑠𝑠 𝑜𝑓 Na(23) + 𝑔𝑟𝑎𝑚 𝑎𝑡𝑜𝑚𝑖𝑐 𝑚𝑎𝑠𝑠 𝑜𝑓 S(32) + 𝑔𝑟𝑎𝑚 𝑎𝑡𝑜𝑚𝑖𝑐 𝑚𝑎𝑠𝑠 𝑜𝑓 O(16)

So, Molar mass of (Na2SO4) is

[(2×23.0)+(32.066)+4(16.00)]=142.066g mol1

Step 3: Calculate of mass percent of each element presents in sodium sulphate

Description:

𝑇ℎ𝑒 𝑚𝑎𝑠𝑠 𝑝𝑒𝑟𝑐𝑒𝑛𝑡 𝑜𝑓 𝑠𝑜𝑑𝑖𝑢𝑚 =2×23142.006×100=32.37932.4%

𝑇ℎ𝑒 𝑚𝑎𝑠𝑠 𝑝𝑒𝑟𝑐𝑒𝑛𝑡 𝑜𝑓 𝑠𝑢𝑙𝑝ℎ𝑢𝑟 =32.066142.006×100=22.5722.6%

𝑇ℎ𝑒 𝑚𝑎𝑠𝑠 𝑝𝑒𝑟𝑐𝑒𝑛𝑡 𝑜𝑓 𝑜𝑥𝑦𝑔𝑒𝑛 =4×16142.006×100=45.04945%

Final Answer:

𝑇ℎ𝑒 𝑚𝑎𝑠𝑠 𝑝𝑒𝑟𝑐𝑒𝑛𝑡 𝑜𝑓 𝑠𝑜𝑑𝑖𝑢𝑚 𝑖𝑛 𝑠𝑜𝑑𝑖𝑢𝑚 𝑠𝑢𝑙𝑝ℎ𝑎𝑡𝑒 =32.4%

𝑇ℎ𝑒 𝑚𝑎𝑠𝑠 𝑝𝑒𝑟𝑐𝑒𝑛𝑡 𝑜𝑓 𝑠𝑢𝑙𝑝ℎ𝑢𝑟 𝑖𝑛 𝑠𝑜𝑑𝑖𝑢𝑚 𝑠𝑢𝑙𝑝ℎ𝑎𝑡𝑒 =22.6%

𝑇ℎ𝑒 𝑚𝑎𝑠𝑠 𝑝𝑒𝑟𝑐𝑒𝑛𝑡 𝑜𝑓 𝑜𝑥𝑦𝑔𝑒𝑛 𝑖𝑛 𝑠𝑜𝑑𝑖𝑢𝑚 𝑠𝑢𝑙𝑝ℎ𝑎𝑡𝑒 =45%

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